Micro-WorldWinter 2021 - Volume 57, Issue 4, Winter 2021, Vol. 57, No. 4

Quarterly Crystal: Rutile on Hematite

John I. Koivula, Nathan Renfro

This Pakistani hematite crystal has a geometric outer skin of rutile.
Figure 1. Measuring 39.83 mm and weighing 178.33 ct, this Pakistani hematite crystal is host to a geometric outer skin of sagenitic rutile. Photo by Diego Sanchez.

When we think of the micro-world of gems and minerals, we usually think of transparent to translucent host materials. However, there are also a number of opaque minerals used as gems that are composed of chemical elements such as copper, iron, and titanium. One of these is hematite.

Recently we had the opportunity to study an unusual hematite crystal sent by Ali Shad of Shad Fine Minerals in Gilgit-Baltistan, Pakistan. The geographic source for the hematite crystal pictured in figure 1 is the Yangslo mine, located in the Basha Valley of Gilgit-Baltistan. At 178.33 ct and 39.83 mm in the longest direction, this “floater” hematite crystal (with no points of attachment to the surrounding rock) plays host to a sagenitic network of epitaxial, surface-oriented, opaque dark gray acicular rutile crystals as large as 4 mm in length.

Rutile crystals in a geometric pattern on the surface of hematite.
Figure 2. The sagenitic epitaxial structure of the acicular rutile crystals on the surface of this hematite gives the substrate an otherworldly appearance. Photomicrograph by Nathan Renfro; field of view 11.28 mm.

Using laser Raman microspectrometry, the identification of the sagenitic crystals was confirmed as rutile. Energy-dispersive X-ray fluorescence (EDXRF) analysis showed the dominant presence of iron and titanium, with a trace of manganese. As shown in figure 2, the euhedral rutile crystals were situated on the hematite crystal in the form of a geometric sagenitic boxwork.

John Koivula is an analytical microscopist, and Nathan Renfro is manager of colored stone identification, at GIA in Carlsbad, California.

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Quarterly Crystal: Rutile on Hematite