Aviat Diamonds: A Window into the Deep Lithospheric Mantle Beneath the Northern Churchill Province, Melville Peninsula, Canada
The FTIR analysis revealed that majority of these samples were type IaAB, including IaA and IaB. Total nitrogen content ranged from 13 to 1467 ppma. The Aviat diamonds were relatively rich in hydrogen. The absorption bands at 3107, 2786, and 1404 cm–1, caused by bending and stretching of the vinylidene group (C=CH2), were observed in most samples. Additional hydrogen-related band at 3237 cm–1 was also detected.
SIMS revealed nitrogen content ranged from 1 to 1724 ppma. The δ13C isotopic analysis suggested that these diamonds were precipitated mainly from carbonate-bearing fluids. Large variations in nitrogen content and δ13C values, although they were not correlated, were observed in growth sectors, suggesting multiple events of fluid derivation from different sources, mainly ecologitic, and also probably peridotitic. However, the relationship between CL and carbon isotopic composition suggested that non-luminescent diamond may have been formed during one episode of growth. The Aviat diamonds were possibly formed from diamond forming fluids or melts from several orogenic events, such as transportation of graphitized organic matters and marine carbonates into deep mantle via subducting oceanic slabs.
The catastrophic platelet degradation was suggested by the positive correlation between platelets and B aggregates of nitrogen. This phenomenon was probably caused by transient heating events or deformation or both during mantle residence. Blue luminescence of nitrogen-rich samples may be related to intense degradation of platelets. The residence temperature of most samples was extrapolated to ~1050–1150°C, suggestive of diamond source near the top of diamond stability field at ~150–170 km.
Abstracted by Kyaw Soe Moe