Inside De Beers’ Lightbox Diamonds
March 18, 2019
De Beers’ line of laboratory-grown diamonds, Lightbox, made its retail debut in the autumn. Shortly afterwards, GIA researcher, Dr Sally Eaton-Magana, who has been identifying and analysing lab-grown diamonds for 11 years, took a close look at the new De Beers-produced product for the Winter 2018 issue of Gems & Gemology.
Lightbox diamonds are produced in quarter carat, half carat and full carat sizes in colourless, pink and blue, and are uniformly priced at $800 (£600) per carat. Eaton-Magana examined two colourless specimens of .24 ct and .26 ct, respectively.
Both stones were of a colour equivalent to G on the GIA diamond colour scale, with cut grades of excellent and very good. Both were of very high clarity, the equivalent of VVS2 on the GIA clarity scale. The smaller diamond had a pinpoint in a bezel facet, while the other had a tiny feather in a star facet. The laser-inscribed Lightbox logo (2 equilateral triangles base to base with an isosceles triangle in the middle) under the table – large enough to be easily visible with a microscope – would reduce the equivalent clarity grade to VS2. GIA Synthetic Diamond Grading Reports use ranges, rather than specific grades, to describe the colour and clarity of laboratory-grown diamonds.
Magana confirmed that the Lightbox diamonds were grown using the chemical vapour deposition (CVD) process, which means they are Type IIa with no detectable nitrogen. “The identification criteria for high pressure, high temperature (HPHT) and CVD synthetics are quite distinct from each other,” she explained, adding that synthetic products have become much more varied over the last 10-15 years.
“When the GIA synthetic diamond grading report was first launched in 2007, CVD synthetics were not commercially available,” she noted. “The commercially available sizes of lab-grown diamonds have expanded such that both very large and very small stones are possible. Also, colourless to near-colourless synthetics were once quite rare and are now the majority seen at the lab.”
Although Lightbox is new to the market, and the variety of lab-grown diamonds is increasing, the fundamental identification criteria have not changed. They are based on growth morphology and optical properties. “We also regularly conduct research on emerging products and GIA has a programme to grow synthetics ourselves to stay ahead of any new trends,” she said.
Similarly, the basic equipment for identification has not changed. Researchers and grading laboratory staff continue to rely on microscopy, fluorescence imaging, absorption spectroscopy and photoluminescence (PL) spectroscopy. What has evolved, she said, is the speed and efficiency of these devices.
The evolution of PL mapping capabilities is important, she explained, because it enables GIA to collect thousands of spectra at micron-sized intervals across the surface of a diamond in mere minutes.
“This technology allows us to map the defect concentrations of synthetic diamond to visualise the growth sectors in HPHT synthetics,” Eaton-Magana explained. “The recent ability to collect many thousands of PL spectra instead of just one spectrum on a diamond gives us opportunities to draw correlations that would not have been previously possible. We have also expanded our research into largely previously unexplored variables – such as what are the effects on spectra within the diamond at various temperatures and timescales; for example, exploring diamond’s luminescence at the nanosecond to millisecond time ranges.”
She said that PL spectra showed the Lightbox diamonds were not subjected to post-growth HPHT processing to improve their colour. The researchers noted that about 75% of all CVD-grown diamonds they encounter have been subjected to such treatment. This is because quite often these diamonds are grown with a brownish colour, especially if the manufacturers attempt to grow them quickly. While the HPHT treatment process is effective in improving the colour of CVD diamonds, the large amount of energy used to create sufficient heat and pressure can add significantly to the cost of production. The Lightbox products, however, are priced much lower than most other lab-grown diamonds in the market.
Both diamonds showed visible red fluorescence in imaging using the DiamondView synthetic detector, but had no detectable fluorescence under long wave UV light. The lab-grown diamonds did show tell-tale CVD growth striations, but they were difficult to spot, requiring careful DiamondView imaging.
Lightbox lab-grown diamonds are readily identifiable as CVD diamonds using spectroscopic techniques, DiamondView imaging and, of course, the inscribed logo under the table, her article noted.
Magana earned her doctoral degree in chemical engineering with Dr John Angus, one of the early pioneers of CVD synthetic diamond growth. For her Ph.D. and post-doctoral work, she worked mainly on growing CVD synthetics for engineering and semiconductor applications.
“While at my post-doc assignment, we collaborated with the Smithsonian Institution to study the phosphorescence of type IIb diamonds in their collection, including the Hope Diamond. With this introduction to gem diamonds, I wanted to transition into this field and was fortunate to obtain a position at GIA following my post-doctoral assignment,” Magana said. “Since then, I have spent much of my time delving into the physics of gem diamonds, concentrating on various treatments and detection methods, and distinguishing synthetics from their natural counterparts.”
Russell Shor is senior industry analyst at GIA in Carlsbad.