Large, Rare Diamonds Reveal the Inner Workings of Earth’s Mantle
December 16, 2016
This is an extended abstract of the article ‘Large Gem Diamonds From Metallic Liquid in Earth’s Deep Mantle,’ published on 16 December 2016 in Science magazine. GIA Postdoctoral Research Fellow Evan Smith is the lead author of the article.
Large and exceptional gem diamonds like the famous Cullinan or Lesotho Promise tend to have a set of physical characteristics that distinguishes them from other kinds of diamonds (fig 1). One of the most noted characteristics is a low nitrogen concentration, such that these diamonds are predominantly type II, although not all type II diamonds necessarily belong to this family. New research published in Science reveals that these Cullinan-like gems, dubbed "CLIPPIR" diamonds, tell us something remarkable about the deep earth1.
The new findings show that CLIPPIR diamonds may have grown from a metallic liquid in Earth’s deep mantle1. This iron-nickel metal is created and stabilised by the high pressure minerals in the deep mantle2,3. Although the amount of metal in these regions of the mantle is likely about 1% or less, it is expected to regulate and limit the availability of oxygen. The distribution and availability of oxygen is one of the key parameters governing the large-scale geological evolution of the Earth4.
This discovery is based on inclusions. As explained in the article1, CLIPPIR diamonds tend to have few inclusions, especially in their cut and polished state, but sometimes they have small metallic inclusions trapped within them (fig 2). The metallic inclusions coexist with traces of fluid methane and hydrogen. In addition to the metallic inclusions, some CLIPPIR diamonds contain mineral inclusions that constrain the depth of origin. These inclusions show the diamonds formed at extreme depths, probably 360–750 km into the convecting mantle. This is much deeper than most other gem diamonds, which form in the lower part of continental tectonic plates at depths of 150–200 km. This new explanation for CLIPPIR diamonds resolves one of the major enigmas in the study of diamond formation—how the world’s very best and biggest diamonds formed.
The composition of the inclusions provides the story. The metallic inclusions are a solidified mixture of iron, nickel, carbon, and sulphur, also containing traces of fluid methane and hydrogen in the thin tiny space between the metallic phases and the encasing diamond1. Originally, this mix was part of a larger mass of molten metallic liquid in the Earth’s deep mantle, from which the pure carbon crystallised to form diamonds. Small droplets of this metallic liquid were occasionally trapped within the diamonds as they grew. During cutting and polishing, the parts of the diamond that contain inclusions are often trimmed off or polished away to craft exquisite gems with minimal flaws. These offcut waste diamond pieces are not normally made available for research, but a special effort was made to obtain offcuts to study the inclusions in this investigation. Diamonds are one of the most valuable scientific tools for studying the deep Earth, which is otherwise completely inaccessible and hidden from our view beneath the tectonic plates.
Previous experiments and theory have predicted for many years that parts of the deep mantle below about 250 km depth contain small amounts of metallic iron and have limited oxygen available2. Now, the metallic inclusions and their surrounding methane and hydrogen jackets in CLIPPIR diamonds provide consistent, systematic physical evidence to support this prediction. Though the extent of metal distribution is uncertain, this is a key observation for our understanding of the Earth and has broad implications for the behaviour of the deep Earth, including the recycling of surface rocks into the convecting mantle, and the deep storage and cycling of carbon and hydrogen in the mantle through geological time.
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Smith, E. M. et al. Large gem diamonds from metallic liquid in Earth's deep mantle. Science in press, doi:10.1126/science.aal1303 (2016).
Frost, D. J. et al. Experimental evidence for the existence of iron-rich metal in the Earth's lower mantle. Nature 428, 409-412, doi:10.1038/nature02413 (2004).
Rohrbach, A. et al. Metal saturation in the upper mantle. Nature 449, 456-458, doi:10.1038/nature06183 (2007).
Rohrbach, A. & Schmidt, M. W. Redox freezing and melting in the Earth's deep mantle resulting from carbon-iron redox coupling. Nature 472, 209-212, doi:10.1038/nature09899 (2011).